All times CAT (SA, GMT+2)
| Tuesday 18 September 2012 |
| Olympiacos | v | Schalke 04 | Karaiskakis Stadium | Video (€6.50) | 20:45 | ||
| Borussia Dortmund | v | Ajax | Signal Iduna Park | Video (€6.50) | 20:45 | ||
| Real Madrid | v | Man City | Santiago Bernabeu | Video (€6.50) | 20:45 | Preview | |
| PSG | v | Dynamo Kiev | Parc des Princes | Video (€6.50) | 20:45 | ||
| Montpellier | v | Arsenal | La Mosson | Video (€6.50) | 20:45 | ||
| AC Milan | v | Anderlecht | San Siro | Video (€6.50) | 20:45 | ||
| Malaga | v | Zenit St Petersburg | La Rosaleda | Video (€6.50) | 20:45 | ||
| Dinamo Zagreb | v | FC Porto | Maksimir Stadium | Video (€6.50) | 20:45 |
| Wednesday 19 September 2012 |
| Lille | v | BATE | Lille Metropole | Video (€6.50) | 20:45 | ||
| Shakhtar Donetsk | v | FC Nordsjaelland | Donbass Arena | Video (€6.50) | 20:45 | ||
| Barcelona | v | Spartak Moscow | Camp Nou | Video (€6.50) | 20:45 | ||
| Braga | v | CFR Cluj-Napoca | Estadio AXA | Video (€6.50) | 20:45 | ||
| Bayern Munich | v | Valencia | Allianz Arena | Video (€6.50) | 20:45 | ||
| Chelsea | v | Juventus | Stamford Bridge | Video (€6.50) | 20:45 | ||
| Man Utd | v | Galatasaray | Old Trafford | Video (€6.50) | 20:45 | ||
| Celtic | v | Benfica | Celtic Park | Video (€6.50) | 20:45 |
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